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The newer transitions in the PDF standard are available, but are not documented.
I could do with a bit more detail here (not being a PDF transition expert): what transitions are we talking about here?
You can find the new page transitions in the PDF specification (http://wwwimages.adobe.com/www.adobe.com/content/dam/Adobe/en/devnet/pdf/pdfs/PDF32000_2008.pdf, page 378): The new transitions, introduced in PDF 1.5, are: